The vibronic intensities for band systems of NO corresponding to transitions with origin in both the X2Π ground and the 3sσ(A2Σ+) Rydberg states, and ending in the npπ Rydberg series with n = 3-5, have been determined. The description of the Rydberg states has been made with the molecular quantum defect orbital methodology. The Rydberg-valence interaction of the 2Π symmetry states involved in the studied transitions has been analyzed through a vibronic matrix. The present results have been compared with experimental and theoretical data available in the literature. Additionally, predictions for a number of unknown intensities have been made, which may be useful for the interpretation of the spectrum of NO.
|Autori:||VELASCO A. M; LAVIN C; BUSTOS E; MARTIN I; GRANUCCI G; PERSICO M|
|Titolo:||Absorption oscillator strengths for vibronic transitions of npp Rydberg series in NO|
|Anno del prodotto:||2010|
|Digital Object Identifier (DOI):||10.1021/jp1045113|
|Appare nelle tipologie:||1.1 Articolo in rivista|