EnglishTwo protocols have been developed for the Pd-catalyzed regioselective synthesis of 4-aryl-3-chloro-2(5H)-furanones starting from 3,4-dichloro-2(5H)-furanone. These monochloro derivatives have then been used as precursors to (Z)-4-aryl-5-[I(aryl)methylidenel-3-chloro-2(5H)-furanones including naturally-occurring rubrolide M. (C) 2002 Elsevier Science Ltd. All rights reserved.
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http://hdl.handle.net/11568/203827| Autori interni: | BELLINA, FABIO ROSSI, RENZO |
| Autori: | Bellina F; Anselmi C; Rossi R |
| Titolo: | Total synthesis of rubrolide M and some of its unnatural congeners |
| Anno del prodotto: | 2002 |
| Abstract: | Two protocols have been developed for the Pd-catalyzed regioselective synthesis of 4-aryl-3-chloro-2(5H)-furanones starting from 3,4-dichloro-2(5H)-furanone. These monochloro derivatives have then been used as precursors to (Z)-4-aryl-5-[I(aryl)methylidenel-3-chloro-2(5H)-furanones including naturally-occurring rubrolide M. (C) 2002 Elsevier Science Ltd. All rights reserved. |
| Digital Object Identifier (DOI): | 10.1016/S0040-4039(02)00202-2 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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