Two protocols have been developed for the Pd-catalyzed regioselective synthesis of 4-aryl-3-chloro-2(5H)-furanones starting from 3,4-dichloro-2(5H)-furanone. These monochloro derivatives have then been used as precursors to (Z)-4-aryl-5-[I(aryl)methylidenel-3-chloro-2(5H)-furanones including naturally-occurring rubrolide M. (C) 2002 Elsevier Science Ltd. All rights reserved.
Autori interni: | |
Autori: | Bellina, Fabio; Anselmi, C; Rossi, Renzo |
Titolo: | Total synthesis of rubrolide M and some of its unnatural congeners |
Anno del prodotto: | 2002 |
Abstract: | Two protocols have been developed for the Pd-catalyzed regioselective synthesis of 4-aryl-3-chloro-2(5H)-furanones starting from 3,4-dichloro-2(5H)-furanone. These monochloro derivatives have then been used as precursors to (Z)-4-aryl-5-[I(aryl)methylidenel-3-chloro-2(5H)-furanones including naturally-occurring rubrolide M. (C) 2002 Elsevier Science Ltd. All rights reserved. |
Digital Object Identifier (DOI): | 10.1016/S0040-4039(02)00202-2 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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