Three different bile acid derived biphenylphosphites were synthesised, starting from cholic and deoxycholic acids and biphenol and their stereochemical features checked by CD and NMR spectroscopies. On the basis of the spectroscopic results the capability of the cholestanic system to induce a prevalent sense of twist on the biphenyl moiety of the bile acid derived phosphites as well as their tropos nature was inferred.

Asymmetric Induction by the Cholestanic Moiety on Tropos Species: Synthesis and Stereochemical Characterization of Bile Acid-Based Biphenyl Phosphites

IULIANO, ANNA;UCCELLO BARRETTA, GLORIA
2006

Abstract

Three different bile acid derived biphenylphosphites were synthesised, starting from cholic and deoxycholic acids and biphenol and their stereochemical features checked by CD and NMR spectroscopies. On the basis of the spectroscopic results the capability of the cholestanic system to induce a prevalent sense of twist on the biphenyl moiety of the bile acid derived phosphites as well as their tropos nature was inferred.
Iuliano, Anna; Facchetti, S; UCCELLO BARRETTA, Gloria
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/203902
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 29
  • ???jsp.display-item.citation.isi??? 26
social impact