EnglishUV irradiation of Pd(P(t)Bu3)2 in n-hexane or THF gives the diamagnetic dinuclear complex [Pd(P(t)Bu2H)(mu-P(t)Bu2)]2, 2-methylpropene, and hydrogen. The complex was also obtained from the reaction of Pd(eta(5)-C5H5)(eta(3)-C3H5) with P(t)Bu2H in toluene. Its crystal and molecular structure were determined by an X-ray diffraction study. Each Pd bears a terminal P(t)Bu2H ligand and the two metal centers are bridged by two phosphido ligands.
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http://hdl.handle.net/11568/20396| Autori interni: | LEONI, PIERO PASQUALI, MARCO |
| Autori: | LEONI P; SOMMOVIGO M; PASQUALI M; SABATINO P; BRAGA D |
| Titolo: | A simple synthesis and crystal structure of the dinuclear diphosphido-bridged palladium(I) complex [Pd(PtBu2H)(µ-PtBu2)]2 |
| Anno del prodotto: | 1992 |
| Digital Object Identifier (DOI): | 10.1016/0022-328X(92)83119-3 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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