UV irradiation of Pd(P(t)Bu3)2 in n-hexane or THF gives the diamagnetic dinuclear complex [Pd(P(t)Bu2H)(mu-P(t)Bu2)]2, 2-methylpropene, and hydrogen. The complex was also obtained from the reaction of Pd(eta(5)-C5H5)(eta(3)-C3H5) with P(t)Bu2H in toluene. Its crystal and molecular structure were determined by an X-ray diffraction study. Each Pd bears a terminal P(t)Bu2H ligand and the two metal centers are bridged by two phosphido ligands.
A simple synthesis and crystal structure of the dinuclear diphosphido-bridged palladium(I) complex [Pd(PtBu2H)(µ-PtBu2)]2
LEONI, PIERO;PASQUALI, MARCO;
1992-01-01
Abstract
UV irradiation of Pd(P(t)Bu3)2 in n-hexane or THF gives the diamagnetic dinuclear complex [Pd(P(t)Bu2H)(mu-P(t)Bu2)]2, 2-methylpropene, and hydrogen. The complex was also obtained from the reaction of Pd(eta(5)-C5H5)(eta(3)-C3H5) with P(t)Bu2H in toluene. Its crystal and molecular structure were determined by an X-ray diffraction study. Each Pd bears a terminal P(t)Bu2H ligand and the two metal centers are bridged by two phosphido ligands.File in questo prodotto:
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