fac-Mo(CO)3(DMF)3, a valuable starting material for the preparation of L(n)Mo(CO)3 complexes, has been prepared in high yields by refluxing Mo(CO)6 in DMF and its crystal and molecular structure determined by X-ray diffraction. The substitution of DMF molecules generally occurs under mild conditions; when this is not the case, the substitution can be facilitated by addition of BF3.Et2O
SYNTHESIS, STRUCTURE AND REACTIVITY OF fac-Mo(CO)3(DMF)3 - EFFECT OF LEWIS-ACIDS ON THE SUBSTITUTION OF DMF LIGANDS
PASQUALI, MARCO;LEONI, PIERO;
1992-01-01
Abstract
fac-Mo(CO)3(DMF)3, a valuable starting material for the preparation of L(n)Mo(CO)3 complexes, has been prepared in high yields by refluxing Mo(CO)6 in DMF and its crystal and molecular structure determined by X-ray diffraction. The substitution of DMF molecules generally occurs under mild conditions; when this is not the case, the substitution can be facilitated by addition of BF3.Et2OFile in questo prodotto:
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