The reactions of the dinuclear cationic complexes [Pd-2(mu-PBu(2)(t))(PR(3))(4)](+) (PR(3) = PCy(2)H, PMe(3)) with CO or isoprene proceed with substitution of one or two phosphine ligands giving the corresponding [Pd-2(mu-PBu(2)(t))(PR(3))(3)(CO)](+) and [Pd-2(mu-PBu(2)(t)) (mu,eta(2),eta(2)-isoprene)(PR(3))(2)](+) cations. [Pa-2(mu-PBu(2)(t))(PCy(2)H)(3)(CO)](+) equilibrates in solution to a mixture of monocarbonyl derivatives arising from bridging phosphido/terminal phosphine interchange. The complexes were characterized by multinuclear 1-D and 2-D NMR spectroscopy. The crystal and molecular structures of [Pd-2(mu-PBu(2)(t))(PCy(2)H)(3)(CO)]BF4 and [Pd-2(mu-PBu(2)(t))(PCy(2)H)(2)(mu,eta(2),eta(2)-isoprene)]CF3SO3 were solved by single-crystal X-ray diffraction studies.
Autori interni: | |
Autori: | LEONI P; MARCO PASQUALI; MILENA SOMMOVIGO; ALBERTO ALBINATI; PAUL S. PREGOSIN; H. RUEGGER |
Titolo: | Proton Lability in Highly Hindered Dinuclear Palladium(I) mu-Phosphido-Secondary Phosphine Complexes. Crystal Structures of [Pd2(mu-PBut2)(PCy2H)3(CO)]BF4 and [Pd2(mu-PBut2)(PCy2H)2(mu,eta2,eta2-isoprene)]BF4 |
Anno del prodotto: | 1996 |
Digital Object Identifier (DOI): | 10.1021/om9509148 |
Appare nelle tipologie: | 1.1 Articolo in rivista |