The reaction of the new D-galactal-derived allylic aziridine 1β with O-nucleophiles (alcohols and monosaccharides) affords, in a high to complete β-stereoselectivity, the corresponding 2,3-unsaturated-β-O-glycosides bearing a β-N-functionality at C(4).
Stereoselective Uncatalyzed Synthesis of 2,3-Unsaturated-4-N-substituted-beta-O-glycosides by Means of a New D-Galactal Derived N-(Mesyl)-aziridine
DI BUSSOLO, VALERIA;FAVERO, LUCILLA;PINESCHI, MAURO;CROTTI, PAOLO
2006-01-01
Abstract
The reaction of the new D-galactal-derived allylic aziridine 1β with O-nucleophiles (alcohols and monosaccharides) affords, in a high to complete β-stereoselectivity, the corresponding 2,3-unsaturated-β-O-glycosides bearing a β-N-functionality at C(4).File in questo prodotto:
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