(Cy3P)2Pd (Cy = C6H11) reacts with PhOH in toluene to give the phenoxopalladium(II) hydride derivative trans-(PhO)(H)Pd(PCy3)2 . PhOH; the crystal structural study has established that the oxygen of the phenoxy group forms a hydrogen bridge with an uncoordinated phenol molecule, and has allowed direct location of the hydride atom (Pd-H, 1.57(2) angstroem)

Oxidative Addition of O-H Bond to a Metal Center - Synthesis and Crystal-Structure of trans-(PhO)(H)Pd(PCY3)2.PhOH

LEONI, PIERO;PASQUALI, MARCO
1987-01-01

Abstract

(Cy3P)2Pd (Cy = C6H11) reacts with PhOH in toluene to give the phenoxopalladium(II) hydride derivative trans-(PhO)(H)Pd(PCy3)2 . PhOH; the crystal structural study has established that the oxygen of the phenoxy group forms a hydrogen bridge with an uncoordinated phenol molecule, and has allowed direct location of the hydride atom (Pd-H, 1.57(2) angstroem)
1987
Braga, D; Sabatino, P; DI BUGNO, C; Leoni, Piero; Pasquali, Marco
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/204649
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact