(Cy3P)2Pd (Cy = C6H11) reacts with PhOH in toluene to give the phenoxopalladium(II) hydride derivative trans-(PhO)(H)Pd(PCy3)2 . PhOH; the crystal structural study has established that the oxygen of the phenoxy group forms a hydrogen bridge with an uncoordinated phenol molecule, and has allowed direct location of the hydride atom (Pd-H, 1.57(2) angstroem)

Oxidative Addition of O-H Bond to a Metal Center - Synthesis and Crystal-Structure of trans-(PhO)(H)Pd(PCY3)2.PhOH

LEONI, PIERO;PASQUALI, MARCO
1987

Abstract

(Cy3P)2Pd (Cy = C6H11) reacts with PhOH in toluene to give the phenoxopalladium(II) hydride derivative trans-(PhO)(H)Pd(PCy3)2 . PhOH; the crystal structural study has established that the oxygen of the phenoxy group forms a hydrogen bridge with an uncoordinated phenol molecule, and has allowed direct location of the hydride atom (Pd-H, 1.57(2) angstroem)
Braga, D; Sabatino, P; DI BUGNO, C; Leoni, Piero; Pasquali, Marco
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/204649
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