The cationic complexes [Pd(eta(3)-allyl){Ph2P(o-C6H4NMe2)}]PF6 (1) and [PdMe(PPh3){Ph2P(o-C6H4NMe2)}]CF3SO3 . C6H6 (2) catalyse, without any added phosphine, the telomerization reaction of 1,3-butadiene with methanol, showing high chemio- (> 95%) and regioselectivity towards the linear 1-methoxy-2,7-octadiene (> 93%). (C) 1999 Elsevier Science B.V. All rights reserved.
Telomerization of butadiene with methanol catalysed by cationic palladium complexes containing a bidentate phosphinoamino ligand
RASPOLLI GALLETTI, ANNA MARIA;SBRANA, GLAUCO
1999-01-01
Abstract
The cationic complexes [Pd(eta(3)-allyl){Ph2P(o-C6H4NMe2)}]PF6 (1) and [PdMe(PPh3){Ph2P(o-C6H4NMe2)}]CF3SO3 . C6H6 (2) catalyse, without any added phosphine, the telomerization reaction of 1,3-butadiene with methanol, showing high chemio- (> 95%) and regioselectivity towards the linear 1-methoxy-2,7-octadiene (> 93%). (C) 1999 Elsevier Science B.V. All rights reserved.File in questo prodotto:
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