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EnglishSalt of the earth: Radical cation salts of monocyclic arenes, including benzene, have been obtained in a reaction where niobium pentafluoride behaves both as an oxidizing agent (conversion into NbF4) and fluoride acceptor (to afford the counterion [Nb2F11]−, see picture). Anion–π-electron density interactions, as revealed by experimental and computational studies, are crucial in providing unprecedented inertness to the radical cations.
| Autori interni: | ||
| Autori: | MARCHETTI F; PINZINO C; ZACCHINI S; PAMPALONI G | |
| Titolo: | Long-Lived Radical Cations of Monocyclic Arenes at Room Temperature Obtained by NbF5 Acting as an Oxidizing Agent and Counterion Precursor | |
| Anno del prodotto: | 2010 | |
| Abstract: | Salt of the earth: Radical cation salts of monocyclic arenes, including benzene, have been obtained in a reaction where niobium pentafluoride behaves both as an oxidizing agent (conversion into NbF4) and fluoride acceptor (to afford the counterion [Nb2F11]−, see picture). Anion–π-electron density interactions, as revealed by experimental and computational studies, are crucial in providing unprecedented inertness to the radical cations. | |
| Digital Object Identifier (DOI): | 10.1002/anie.201001572 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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