Air oxidation of the phosphido-bridged Pd(I) dimer [Pd2(mu-PtBu2)(PMe3)4](CF3SO3) gives the hydroxo-bridged Pd(II) dinuclear derivative [(Me3P)2Pd(mu-OH)2Pd(PMe3)2](CF3SO3)2 (1) with a low yield. The same cation was obtained with a high yield by the reaction of [PdCl2(PMe3)2] with silver nitrate in wet acetone. The crystal structure of 1 was determined
OXIDATION OF PALLADIUM(I) DIMERS - FORMATION AND X-RAY CRYSTAL-STRUCTURE OF [(Me3P)2Pd(mu-OH)2Pd(PMe3)2](CF3SO3)(2)
PASQUALI, MARCO;LEONI, PIERO;
1995-01-01
Abstract
Air oxidation of the phosphido-bridged Pd(I) dimer [Pd2(mu-PtBu2)(PMe3)4](CF3SO3) gives the hydroxo-bridged Pd(II) dinuclear derivative [(Me3P)2Pd(mu-OH)2Pd(PMe3)2](CF3SO3)2 (1) with a low yield. The same cation was obtained with a high yield by the reaction of [PdCl2(PMe3)2] with silver nitrate in wet acetone. The crystal structure of 1 was determinedFile in questo prodotto:
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