[Pd2(mu-PCy2)(mu,eta3-C3H5)(PCy2H)2] reacts with an excess of PhSH to yield the mononuclear complex trans-[Pd(SPh)2(PCY2H)2] which was completely characterized by solution multinuclear NMR spectroscopy and by a single-crystal X-ray diffraction experiment. Crystal data: for trans-[Pd(SPh)2(PCy2H)2]: triclinic, space group P1BAR, a = 10.061(3), b = 13.733(3), c = 14.398(4) angstrom, alpha = 86.46(4), beta = 72.07(2), gamma = 76.57(4)-degrees, U = 1840.9(9) angstrom3, Z = 2, d(calc) = 1.301 g cm-1, R = 0.064, R' = 0.050.
Disruption of the Pd(I)-Pd(I) dinuclear structure by reaction of [Pd2(mu-PCy2)(mu- eta-3-C3H5)(PCy2H)2] with benzenethiol: formation and x-ray and NMR characterization of trans- [Pd(SPh)2(PCy2H)2].
PASQUALI, MARCO;MARCHETTI, FABIO;LEONI, PIERO;
1993-01-01
Abstract
[Pd2(mu-PCy2)(mu,eta3-C3H5)(PCy2H)2] reacts with an excess of PhSH to yield the mononuclear complex trans-[Pd(SPh)2(PCY2H)2] which was completely characterized by solution multinuclear NMR spectroscopy and by a single-crystal X-ray diffraction experiment. Crystal data: for trans-[Pd(SPh)2(PCy2H)2]: triclinic, space group P1BAR, a = 10.061(3), b = 13.733(3), c = 14.398(4) angstrom, alpha = 86.46(4), beta = 72.07(2), gamma = 76.57(4)-degrees, U = 1840.9(9) angstrom3, Z = 2, d(calc) = 1.301 g cm-1, R = 0.064, R' = 0.050.File in questo prodotto:
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