The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.

CN Bond-Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature

DOLCI, SARA;MARCHETTI, FABIO;PAMPALONI, GUIDO;
2011

Abstract

The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.
Dolci, Sara; Marchetti, Fabio; Pampaloni, Guido; Zacchini, S.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/206056
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