EnglishThe acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5.
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http://hdl.handle.net/11568/206056| Autori interni: | DOLCI, SARA MARCHETTI, FABIO PAMPALONI, GUIDO |
| Autori: | DOLCI S; MARCHETTI F; PAMPALONI G; ZACCHINI S |
| Titolo: | CN Bond-Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature |
| Anno del prodotto: | 2011 |
| Abstract: | The acylamidinium complex MoOCl4[MeC(O)N(Ph)C(Me)=NHPh] (2) was obtained by selective self-condensation of MeC(0)NHPh promoted by MoCl5. Otherwise, the stable chloroiminium salt [MoOCl4{HC(O)NMe2}][CH(Cl)=NMe2] (3) was isolated from HC(O)NMe2/MoCl5. |
| Digital Object Identifier (DOI): | 10.1021/ic2001199 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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