-Benzyl aldehydes are prepared from easily available -silylalkenals and fluoride reagents, under mild experimental conditions; the reaction occurs instantaneously with almost quantitative yields. A plausible mechanism is suggested, which involves a 1,2-phenyl migration from the silicon to the adjacent carbon atom.

New synthesis of alfa-benzylaldehydes from 2-(dimethylphenylsilylmethylene)alkanals by fluoride promoted phenyl migration

ARONICA, LAURA ANTONELLA;CAPORUSSO, ANNA MARIA;SALVADORI, PIERO
2002

Abstract

-Benzyl aldehydes are prepared from easily available -silylalkenals and fluoride reagents, under mild experimental conditions; the reaction occurs instantaneously with almost quantitative yields. A plausible mechanism is suggested, which involves a 1,2-phenyl migration from the silicon to the adjacent carbon atom.
Aronica, LAURA ANTONELLA; Morini, F.; Caporusso, ANNA MARIA; Salvadori, Piero
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/206213
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