An optically active Mn(III)–salen complex was supported on silica gel materials: the insoluble systems obtained were employed as catalysts in the asymmetric epoxidation of some aromatic olefins. Enantiomeric excess values up to 58% were obtained.
|Autori:||Pini, Dario; Mandoli, Alessandro; S., Orlandi; Salvadori, Piero|
|Titolo:||First Example of Silica Gel-Supported Optically Active Mn(III)-salen Complex as a Heterogeneous Asymmetric Catalyst in the Epoxidation of Olefins|
|Anno del prodotto:||1999|
|Digital Object Identifier (DOI):||10.1016/S0957-4166(99)00426-7|
|Appare nelle tipologie:||1.1 Articolo in rivista|