The preparation and properties of some phthalocyanine (pc)-carbonyl derivatives [Fe(pc)(CO)L] [L =dimethylformamide (dmf), tetrahydrofuran, dimethylsulphoxide, ammonia, and PrnNH,] are reported, the first compound in the series being obtained directly from the reaction of [Fe(CO),J with o-C,H,(CN), in dmf.
Reaction of Pentacarbonyliron(0) with Phthalodinitrile in Dimethylformamide and Isolation of Carbonyl Derivatives of Iron(II) Phthalocyanine Stabilized by Group 6 Donor Atoms
CALDERAZZO, FAUSTO;PAMPALONI, GUIDO;
1979-01-01
Abstract
The preparation and properties of some phthalocyanine (pc)-carbonyl derivatives [Fe(pc)(CO)L] [L =dimethylformamide (dmf), tetrahydrofuran, dimethylsulphoxide, ammonia, and PrnNH,] are reported, the first compound in the series being obtained directly from the reaction of [Fe(CO),J with o-C,H,(CN), in dmf.File in questo prodotto:
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