Pd(PBut2H)3, obtained by reacting Pd-(eta5-C5H5)(eta3-C3H5) With PBut2H, oxidatively adds the C-Cl bond of methylene chloride and of chloroform, giving the thermally stable derivatives trans-[PdCl(CH2Cl)(PBut2H)2], (2) and trans-[PdCl(CHCl2)(PBut2H)2], (3), respectively. Complex 1 solutions deposit, by gentle warming, the known dimer [Pd(mu-PBut2)(PBut2H)]2.
The First Palladium (0) Complex with Only Secondary Phosphines as Ligands and Its Oxidative-Addition Reactions with CH2Cl2 and CHCl3, Giving the Thermally Stable Derivatives trans-[PdCl(R)(PBut2H)2] (R = CH2Cl, CHCl2)
LEONI, PIERO
1993-01-01
Abstract
Pd(PBut2H)3, obtained by reacting Pd-(eta5-C5H5)(eta3-C3H5) With PBut2H, oxidatively adds the C-Cl bond of methylene chloride and of chloroform, giving the thermally stable derivatives trans-[PdCl(CH2Cl)(PBut2H)2], (2) and trans-[PdCl(CHCl2)(PBut2H)2], (3), respectively. Complex 1 solutions deposit, by gentle warming, the known dimer [Pd(mu-PBut2)(PBut2H)]2.File in questo prodotto:
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