Free energies and enthalpies of solvation of water and some hydrocarbons (hexane, cyclohexane), ethers (diethyl ether, tetrahydrofuran) and ketones (propanone, pentan-3-one, cyclopentanone) in octan-1-ol have been determined at 298.15 K from vapour-pressure measurements of dilute solutions and from limiting heats of solution. These solvation functions in octanol have been used together with the corresponding hydration functions in order to obtain water–octan-1-ol partition coefficients and their dependence on temperature. A comparison is made with the practical partition coefficients relative to mutually saturated solvents.
|Autori:||P. BERTI;S. CABANI;G. CONTI;V. MOLLICA|
|Titolo:||Thermodynamic Study of Organic-compounds In Octan-1-ol - Processes of Transfer From Gas and From Dilute Aqueous-solution|
|Anno del prodotto:||1986|
|Digital Object Identifier (DOI):||10.1039/f19868202547|
|Appare nelle tipologie:||1.1 Articolo in rivista|