Re2(CO)10 has been obtained in yields as high as 80% by the reaction of Re2O7 or NH4ReO4 with hydrogen-rich CO/H-2 mixtures at 15 MPa and 150-degrees-C in an organic solvent, being the capability to generate in situ well-dispersed rhenium metal the key to obtain Re2(CO)10.
A NOVEL SYNTHESIS OF RE2(CO)10 BY H2/CO REDUCTION OF RE2O7
RASPOLLI GALLETTI, ANNA MARIA;
1993-01-01
Abstract
Re2(CO)10 has been obtained in yields as high as 80% by the reaction of Re2O7 or NH4ReO4 with hydrogen-rich CO/H-2 mixtures at 15 MPa and 150-degrees-C in an organic solvent, being the capability to generate in situ well-dispersed rhenium metal the key to obtain Re2(CO)10.File in questo prodotto:
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