Linear and non-linear Electron Spin Resonance spectroscopies have been designed to study the decay of the orientation correlations on different time scales. The reorientation of radicals (<<spin probes>>) dissolved in host phases (in the present case a polymeric liquid crystal (PLC)) may be investigated in the time window 10(-11)-10(-5) s. Evidence of the non-exponential regression of fluctuations is given. The temperature dependence of the correlation time of the spin probe orientation is discussed in the case of semi-crystalline PLCs and contrasted with the case of amorphous PLCs.

A LINEAR AND NONLINEAR ELECTRON-SPIN-RESONANCE STUDY OF ORIENTATIONAL RELAXATION IN SEMICRYSTALLINE POLYMERIC LIQUID-CRYSTALS

ANDREOZZI, LAURA;GIORDANO, MARCO;LEPORINI, DINO
1994

Abstract

Linear and non-linear Electron Spin Resonance spectroscopies have been designed to study the decay of the orientation correlations on different time scales. The reorientation of radicals (<>) dissolved in host phases (in the present case a polymeric liquid crystal (PLC)) may be investigated in the time window 10(-11)-10(-5) s. Evidence of the non-exponential regression of fluctuations is given. The temperature dependence of the correlation time of the spin probe orientation is discussed in the case of semi-crystalline PLCs and contrasted with the case of amorphous PLCs.
Andreozzi, Laura; Giordano, Marco; Leporini, Dino
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/235140
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