A series of ethers has been prepared whose structures are related to tetrahydropyranyl and tetrahydrofuranyl derivatives with floral odors by replacement of either one of the two oxygen atoms with a methylene group. 2-Substituted tetrahydropyrans and tetrahydrofurans, as well as cyclohexyl and cyclopentyl ethers, have thus been obtained by substitution of the exocyclic or the endocyclic oxygen, respectively. None of the compounds exhibited a pure floral odor, although in several of them this note was present as a secondary character. The data contribute to a better understanding between structure and floral odor.
|Autori:||ANSELMI C; CENTINI M; MARIANI M; NAPOLITANO E; SEGA A; PELOSI P|
|Titolo:||SYNTHESIS OF ETHERS RELATED TO SOME FLORAL ODORANTS - EFFECT OF OXYGEN/CARBON REPLACEMENT|
|Anno del prodotto:||1994|
|Digital Object Identifier (DOI):||10.1021/jf00048a042|
|Appare nelle tipologie:||1.1 Articolo in rivista|