Mixed-valence iodide-bridged compounds of rhenium have been obtained by the di-iodine oxidation of rhenium(I) carbonyl complexes; the X-ray crystal and molecular structure of Re3I6(CO)6, a Re I-ReIV complex of S6 symmetry, is presented.
Synthesis and Molecular Structure of Mixed-valence Compounds of Rhenium obtained by Di-iodine Oxidation of Rhenium(I) Carbonyl Complexes; X-ray Crystal Structure of [Re3I6(CO)6]
CALDERAZZO, FAUSTO;MARCHETTI, FABIO;VITALI, DARIO;
1981-01-01
Abstract
Mixed-valence iodide-bridged compounds of rhenium have been obtained by the di-iodine oxidation of rhenium(I) carbonyl complexes; the X-ray crystal and molecular structure of Re3I6(CO)6, a Re I-ReIV complex of S6 symmetry, is presented.File in questo prodotto:
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