Upon treatment with the K- and Li-enolates of a methylene active compound, such as dimethyl malonate and dibenzoylmethane, D-allal- and D-galactal-derived vinyl N-mesyl aziridines are stereoselectively transformed, in a unique step, into diastereoisomeric, highly functionalized, enantiopure cis-2,5-disubstituted N-mesyl-2,5-dihydropyrroles.
Enantiopure Cis-2,5-Disubstituted 2,5-Dihydropyrroles from d-Glycal-Derived Vinyl Aziridines
DI BUSSOLO, VALERIA;UCCELLO BARRETTA, GLORIA;BALZANO, FEDERICA;PINESCHI, MAURO;
2013-01-01
Abstract
Upon treatment with the K- and Li-enolates of a methylene active compound, such as dimethyl malonate and dibenzoylmethane, D-allal- and D-galactal-derived vinyl N-mesyl aziridines are stereoselectively transformed, in a unique step, into diastereoisomeric, highly functionalized, enantiopure cis-2,5-disubstituted N-mesyl-2,5-dihydropyrroles.File in questo prodotto:
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