Copper(I) chloride reacts with 2,6-But2C6H3ONa in the presence of p-MeC6H4NC to give [(p-MeC6H4NC)2Cu(2,6-But2C6H3O)] containing a tri-coordinated copper(I) atom [Cu–O, 1.917(3)Å], while the solution obtained from ‘CuCOCl’ and 2,6-Me2C6H3ONa reacts with PhCH[double bond, length half m-dash]N–CH2CH2–N[double bond, length half m-dash]CHPh, BEN, to give the diphenoxocuprate(I)[Cu(BEN)2]+[(2,6-Me2C6H3O)2Cu]–[Cu–O, 1.806(6) and 1.798(8)Å].
Monomeric alkoxo complexes of copper(I): syntheses and structures of di(p-tolyl isocyanide)(2,6-di-t-butylphenoxo)copper(I) and a di(2,6-dimethylphenoxo)cuprate(I)
PASQUALI, MARCO;
1984-01-01
Abstract
Copper(I) chloride reacts with 2,6-But2C6H3ONa in the presence of p-MeC6H4NC to give [(p-MeC6H4NC)2Cu(2,6-But2C6H3O)] containing a tri-coordinated copper(I) atom [Cu–O, 1.917(3)Å], while the solution obtained from ‘CuCOCl’ and 2,6-Me2C6H3ONa reacts with PhCH[double bond, length half m-dash]N–CH2CH2–N[double bond, length half m-dash]CHPh, BEN, to give the diphenoxocuprate(I)[Cu(BEN)2]+[(2,6-Me2C6H3O)2Cu]–[Cu–O, 1.806(6) and 1.798(8)Å].File in questo prodotto:
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