STUDIES ON CARBONYL DERIVATIVES OF EARLY TRANSITION-ELEMENTS - A CONVENIENT METHOD FOR THE PREPARATION OF THE [NB(CO)6]- ANION AT ATMOSPHERIC-PRESSURE AND ROOM-TEMPERATURE - CRYSTAL AND MOLECULAR-STRUCTURE OF [NB(CO)6]-,[TA(CO)6]- AS THEIR "BIS(TRIPHENYLPHOSPHINE)NITROGEN(1+) DERIVATIVES