The 1:1 molar reaction of WCl6 with tribenzylamine selectively affords equimolar amounts of the relevant iminium and ammonium [WCl6]− salts via amine-to-tungsten electron transfer and provides a rare example of well-understood interaction of a tertiary amine with a high-valent metal halide.
Tribenzylamine C-H Activation and Intermolecular Hydrogen Transfer Promoted by WCl6
MARCHETTI, FABIO;PAMPALONI, GUIDO;
2014
Abstract
The 1:1 molar reaction of WCl6 with tribenzylamine selectively affords equimolar amounts of the relevant iminium and ammonium [WCl6]− salts via amine-to-tungsten electron transfer and provides a rare example of well-understood interaction of a tertiary amine with a high-valent metal halide.File in questo prodotto:
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