(Z)-13-hexadecen-11-yn-1-yl acetate (2), the sex pheromone of Thaumetopoea pytyocampa, and (5Z,7E)-5,7-dodecadien-1-ol (3), a sex pheromone component of Malacosoma disstria, have been prepared in high chemical and stereoisomeric purity by synthetic schemes involving the stereospeific coupling of ω-functionalized 1-alkynes with (Z)- or (E)-1-iodo-1-alkenes in the presence of a catalytic amount of (PPh3)4Pd and Cul, under phase transfer conditions.

Stereospecific synthesis of (Z)-13-hexadecen-11-yn-1-yl acetate. The sex pheromone of the processionary moth, and of (5Z,7E)-5,7-dodecadien-1-ol, a sex pheromone component of the forest tent caterpillar

ROSSI, RENZO;CARPITA, ADRIANO
1983

Abstract

(Z)-13-hexadecen-11-yn-1-yl acetate (2), the sex pheromone of Thaumetopoea pytyocampa, and (5Z,7E)-5,7-dodecadien-1-ol (3), a sex pheromone component of Malacosoma disstria, have been prepared in high chemical and stereoisomeric purity by synthetic schemes involving the stereospeific coupling of ω-functionalized 1-alkynes with (Z)- or (E)-1-iodo-1-alkenes in the presence of a catalytic amount of (PPh3)4Pd and Cul, under phase transfer conditions.
Rossi, Renzo; Carpita, Adriano
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/4309
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