The "Ritz" computer program, developed for facilitating the assignment of molecular Fourier transform absorption spectra and described in a previous work, determines the energy level values involved in the assigned transitions by the Rydberg-Ritz combination principle. Combining the data obtained from the analyses of high-resolution infrared (IR) and far-infrared (FLR) spectra, it is possible to predict possible FIR laser emissions of molecules. In the present work we have applied this method to the common isotopomer methanol, (CH3)-C-12 (OH)-O-16, and obtained 14 proposed assignments for previously unassigned FIR laser lines. We also predict 15 possible new FIR laser emissions. For the first time, an assignment involving a four-level laser system with collisional population transfer to a slightly higher energy level is reported. (C) 1998 Academic Press.
|Autori interni:||CARELLI, GIORGIO|
|Autori:||Moraes JCS; Carelli G; Moretti A; Moruzzi G; Strumia F|
|Titolo:||Methanol laser line assignments: Evidence of four-level laser systems|
|Anno del prodotto:||1998|
|Digital Object Identifier (DOI):||10.1006/jmsp.1997.7485|
|Appare nelle tipologie:||1.1 Articolo in rivista|