Treatment of [M(CO)J - with HX (X = CI, AcO) under anhydrous conditions or in aqueous buffered solution yielded the diamagnetic [M2(C0)8X3-] anions of d4 niobium([) and tantalum(!); the crystal and molecular structure of the title compound was solved by X-ray diffraction methods, showing that each niobium centre is heptaco-ordinated to four terminal carbonyl groups and to three bridging chlorides.

ANOMALOUS BEHAVIOR OF [NB(CO)6]- AND [TA(CO)6]- TOWARDS PROTONS - CRYSTAL AND MOLECULAR-STRUCTURE OF THE ORGANO-METALLIC ACID [C4H8OH]+[NB2(CO)8CL3]-.C4H8O

CALDERAZZO, FAUSTO;PAMPALONI, GUIDO;
1982

Abstract

Treatment of [M(CO)J - with HX (X = CI, AcO) under anhydrous conditions or in aqueous buffered solution yielded the diamagnetic [M2(C0)8X3-] anions of d4 niobium([) and tantalum(!); the crystal and molecular structure of the title compound was solved by X-ray diffraction methods, showing that each niobium centre is heptaco-ordinated to four terminal carbonyl groups and to three bridging chlorides.
Calderazzo, Fausto; Pampaloni, Guido; Zanazzi, Pf
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/4662
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