Homologation of MeOAc with CO and H2 to give EtOAc was catalyzed by a Ru compd. with a hard acid promoter and, optionally, an iodized compd. Thus, Ru(acac)3, AlI3, MeOAc, and HOAc were treated with CO-H2 (mol ratio 1:2) at 200° and initial pressure 150 atm with agitation for 10 h. The reaction gave 57% conversion of MeOAc with 43.5% selectivity for EtOAc.

Ethyl acetate by homologation of methyl acetate

RASPOLLI GALLETTI, ANNA MARIA;
1984

Abstract

Homologation of MeOAc with CO and H2 to give EtOAc was catalyzed by a Ru compd. with a hard acid promoter and, optionally, an iodized compd. Thus, Ru(acac)3, AlI3, MeOAc, and HOAc were treated with CO-H2 (mol ratio 1:2) at 200° and initial pressure 150 atm with agitation for 10 h. The reaction gave 57% conversion of MeOAc with 43.5% selectivity for EtOAc.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/4676
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