Both enantiomers of (+/-)-9,10-epoxystearic acid (1b), cis-(+/-)-5,6-epoxyhexadecane (1c) and cis-(+/-)-11,12-epoxyhexadecan-1-ol (1d) as well as the meso cis-9,10-epoxyoctadecane (1a) undergo microsomal epoxide hydrolase catalyzed hydration at the (S) carbon to give the corresponding (R,R) threo diols in a >90 e.e. Copyright (C) 1996 Elsevier Science Ltd
Enantioconvergent transformation of racemic cis-dialkyl substituted epoxides to (R,R) threo diols by microsomal epoxide hydrolase catalysed hydrolysis
CHIAPPE, CINZIA;
1996-01-01
Abstract
Both enantiomers of (+/-)-9,10-epoxystearic acid (1b), cis-(+/-)-5,6-epoxyhexadecane (1c) and cis-(+/-)-11,12-epoxyhexadecan-1-ol (1d) as well as the meso cis-9,10-epoxyoctadecane (1a) undergo microsomal epoxide hydrolase catalyzed hydration at the (S) carbon to give the corresponding (R,R) threo diols in a >90 e.e. Copyright (C) 1996 Elsevier Science LtdFile in questo prodotto:
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