Thermodynamic Analysis and Possible Applications of the Integrated Pyrolysis Fuel Cell Plant (IPFCP)

Biomass and waste are generally considered as a very promising option for fossil fuel substitution and greenhouse effect reduction in a sustainable energy scenario. This paper examines the possible lay-out and performance of an innovative energy system based on the integration of a high temperature fuel cell with a pyrolysis reactor. The pyrolyzer converts biomass or solid waste into syngas, which is cleaned from impurities and feeds a Solid Oxide Fuel Cell (SOFC), operating at 1000°C. A combustor supplies the energy required for pyrolysis, burning the solid and liquid fraction of the pyrolysis yield, as well as the un-oxidized fuel leaving the cell anode. Literature data have been used for determining pyrolysis yield as a function of reactor temperature and evaluating its effect on the plant thermodynamic efficiency. The coupling of the system to a gas turbine using the fuel cell as its combustion chamber is also evaluated. Results show that very interesting efficiencies are obtainable in the 20%–30% range.