The title compd. (I) was prepd. from D-mannitol by isopropylidenation, Pb(OAc)4 oxidn., redn., Grignard reaction with Me2CHCl, and bromination-dehydrobromination of II. Grignard reaction of I with CH2:CHCCl:CH2 gave (S)-ipsenol.
Synthesis of enantiomerically pure (S)-1,2-epoxy-4-methylpentane starting from D-mannitol
ROSSI, RENZO;CARPITA, ADRIANO;
1983-01-01
Abstract
The title compd. (I) was prepd. from D-mannitol by isopropylidenation, Pb(OAc)4 oxidn., redn., Grignard reaction with Me2CHCl, and bromination-dehydrobromination of II. Grignard reaction of I with CH2:CHCCl:CH2 gave (S)-ipsenol.File in questo prodotto:
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