The reaction of 1,1,3,3-tetraethylurea (teu) with WCl6 in dichloromethane afforded [teuH][WCl6], 1, in 50–60% yield. The X-ray structure determined for 1 includes the first example of crystallographic characterization of a N-protonated urea. According to spectroscopic and DFT outcomes, the formation of 1 is the result of an electron transfer/C–H activation process.
A crystallographically characterized salt of self-generated N-protonated tetraethylurea
MARCHETTI, FABIO;PAMPALONI, GUIDO;
2015-01-01
Abstract
The reaction of 1,1,3,3-tetraethylurea (teu) with WCl6 in dichloromethane afforded [teuH][WCl6], 1, in 50–60% yield. The X-ray structure determined for 1 includes the first example of crystallographic characterization of a N-protonated urea. According to spectroscopic and DFT outcomes, the formation of 1 is the result of an electron transfer/C–H activation process.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
98 - Chem Commun 2015 - ureaH.pdf
solo utenti autorizzati
Tipologia:
Versione finale editoriale
Licenza:
Tutti i diritti riservati (All rights reserved)
Dimensione
1.44 MB
Formato
Adobe PDF
|
1.44 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
|
98 Chem Commun.pdf
accesso aperto
Tipologia:
Documento in Pre-print
Licenza:
Tutti i diritti riservati (All rights reserved)
Dimensione
240.18 kB
Formato
Adobe PDF
|
240.18 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
