Redox reactions of V(CO)6w ith [Co(CO)4]-, [Mn(CO)5]-, [M2(C0),012-,o r [M(T~-C~H~) (C(OM) =~ ]C-r , Mo, W), or C O ( ~ ~ - Co~ccHur~ ra)p~id ly at 25 "C and lower in hydrocarbons; on the other hand, V(C0)s is oxidized to V(T-~-C~H~)(CbOy )M, n(q5-C5H5)o* r N i ( ~ f - c ~ Han~d )th~e two-electron oxidation of [Nb(CO)6]- to the [Nb2X3(C0)8]a- nion (X = CI, Br, I, acetylacetonato), can be carried out using a number of oxidizing agents (Hgll, Cull, Cul, Agl, or Fell').
REDOX REACTIONS OF METAL-CARBONYLS OF GROUP-5A
CALDERAZZO, FAUSTO;PAMPALONI, GUIDO
1984-01-01
Abstract
Redox reactions of V(CO)6w ith [Co(CO)4]-, [Mn(CO)5]-, [M2(C0),012-,o r [M(T~-C~H~) (C(OM) =~ ]C-r , Mo, W), or C O ( ~ ~ - Co~ccHur~ ra)p~id ly at 25 "C and lower in hydrocarbons; on the other hand, V(C0)s is oxidized to V(T-~-C~H~)(CbOy )M, n(q5-C5H5)o* r N i ( ~ f - c ~ Han~d )th~e two-electron oxidation of [Nb(CO)6]- to the [Nb2X3(C0)8]a- nion (X = CI, Br, I, acetylacetonato), can be carried out using a number of oxidizing agents (Hgll, Cull, Cul, Agl, or Fell').File in questo prodotto:
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