The nickel(II) complex of a new bis-N,O-bidentate Schiff base, in which two salicylaldiminate units are connected by an alpha,alpha'-dioxo-ortho-xylidene spacer via the 3-position of salicyl moieties, was structurally characterised in the solid state and in solution as a dinuclear double helicate based on a square-planar coordination geometry.
A Self-Assembled Dinuclear Double-Stranded Helicate Based on a Square-Planar Coordination Geometry
ISOLA, MAURO;MARCHETTI, FABIO;
2002-01-01
Abstract
The nickel(II) complex of a new bis-N,O-bidentate Schiff base, in which two salicylaldiminate units are connected by an alpha,alpha'-dioxo-ortho-xylidene spacer via the 3-position of salicyl moieties, was structurally characterised in the solid state and in solution as a dinuclear double helicate based on a square-planar coordination geometry.File in questo prodotto:
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