The [Dy(tta)3(L)] complex behaves as a single ion magnet both in its crystalline phase and in solution. Experimental and theoretical magnetic anisotropy axes perfectly match and lie along the most electro-negative atoms of the coordination sphere. Both VSM and MCD measurements highlight the robustness of the complex, with persistence of the memory effect even in solution up to 4 K. © 2013 American Chemical Society.
Magnetic poles determinations and robustness of memory effect upon solubilization in a DyIII-based single ion magnet
PINEIDER, FRANCESCO;
2013-01-01
Abstract
The [Dy(tta)3(L)] complex behaves as a single ion magnet both in its crystalline phase and in solution. Experimental and theoretical magnetic anisotropy axes perfectly match and lie along the most electro-negative atoms of the coordination sphere. Both VSM and MCD measurements highlight the robustness of the complex, with persistence of the memory effect even in solution up to 4 K. © 2013 American Chemical Society.File in questo prodotto:
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