The paper reports on the synthesis and characterization of a new chiral alkyl vinyl ether derived from the head-to-tail dimer of (S)-1,2-propanediol having high optical purity. The prepared vinyl ether has been polymerized in the presence of different cationic catalysts and the polymer optical rotation has been reported and commented in respect to the structure of the starting monomer.
A new chiral poly(alkyl vinyl ether): synthesis and chiroptical properties
CHIELLINI, EMO;SOLARO, ROBERTO
1988-01-01
Abstract
The paper reports on the synthesis and characterization of a new chiral alkyl vinyl ether derived from the head-to-tail dimer of (S)-1,2-propanediol having high optical purity. The prepared vinyl ether has been polymerized in the presence of different cationic catalysts and the polymer optical rotation has been reported and commented in respect to the structure of the starting monomer.File in questo prodotto:
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