Amphiphilic modified-styrene copolymer films: Antifouling/fouling release properties against the green alga Ulva linza

Surface-active copolymers of a styrene carrying a polysiloxane side chain (SSi) and a triethyleneglycol monomethyl ether-modified pentafluorostyrene (EFS) (39 and 77 mol% EFS) were prepared and incorporated (8 wt% loading) into a polydimethyl siloxane (PDMS) matrix to produce crosslinked blend films. The wettability of the surface-active copolymer films and PDMS-blend films was investigated by contact angle measurements. An angle-resolved X-ray photoelectron spectroscopy (XPS) of the surface chemical composition before and after immersion in water for 7 days enabled location of the hydrophilic oxyethylenic segments of EFS within the top 10 nm from the film surface. Laboratory bioassays on the blend films against the marine green alga Ulva linza evidenced that the films containing the copolymer with the larger EFS content showed greater resistance to settlement of zoospores of U. linza, whereas both films had superior fouling-release properties of sporelings (young plants) compared to the PDMS standard films.