(E)-1-Trimethylsilyl-3-en-1-ynes have been diastereoselectively synthesized starting from stereoisomeric mixtures of 1-bromo-1-alkenes. The procedure has been employed to prepare (2E,6E)-1-acetoxy-2,6-decadien-4-yne, a naturally-occuring acetylenic compound.

Diastereoselective synthesis of (E)-1-trimethylsilyl-3-en-1-ynes by palladium-catalyzed cross-coupling reaction between trimethylsilylethynylzinc chloride and stereoisomeric mixtures of 1-bromo-1-alkenes

CARPITA, ADRIANO;ROSSI, RENZO
1986

Abstract

(E)-1-Trimethylsilyl-3-en-1-ynes have been diastereoselectively synthesized starting from stereoisomeric mixtures of 1-bromo-1-alkenes. The procedure has been employed to prepare (2E,6E)-1-acetoxy-2,6-decadien-4-yne, a naturally-occuring acetylenic compound.
Andreini, B. P; Carpita, Adriano; Rossi, Renzo
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/7936
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? 37
social impact