(E)-1-Trimethylsilyl-3-en-1-ynes have been diastereoselectively synthesized starting from stereoisomeric mixtures of 1-bromo-1-alkenes. The procedure has been employed to prepare (2E,6E)-1-acetoxy-2,6-decadien-4-yne, a naturally-occuring acetylenic compound.

Diastereoselective synthesis of (E)-1-trimethylsilyl-3-en-1-ynes by palladium-catalyzed cross-coupling reaction between trimethylsilylethynylzinc chloride and stereoisomeric mixtures of 1-bromo-1-alkenes

CARPITA, ADRIANO;ROSSI, RENZO
1986-01-01

Abstract

(E)-1-Trimethylsilyl-3-en-1-ynes have been diastereoselectively synthesized starting from stereoisomeric mixtures of 1-bromo-1-alkenes. The procedure has been employed to prepare (2E,6E)-1-acetoxy-2,6-decadien-4-yne, a naturally-occuring acetylenic compound.
1986
Andreini, B. P; Carpita, Adriano; Rossi, Renzo
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/7936
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