A tropos deoxcholic acid derived diamidophosphite was synthesised starting from deoxycholic acid and N,N′-dimethyl-2,2′-diamino-1,1′biphenyl and its stereodinamic characteristics were assessed by VT-NMR spectroscopy. The capability of the diamidophosphite to act as Rh-ligand was investigated in the formation of ionic as well as covalent Rh-complexes. The stereodinamic properties of these complexes were studied by VT-NMR spectroscopy.
Asymmetric activation of the tropos biphenyldiamidophosphite moiety: Synthesis and complexation to rhodium of a deoxycholic acid derived diamidophosphite
IULIANO, ANNA
2016-01-01
Abstract
A tropos deoxcholic acid derived diamidophosphite was synthesised starting from deoxycholic acid and N,N′-dimethyl-2,2′-diamino-1,1′biphenyl and its stereodinamic characteristics were assessed by VT-NMR spectroscopy. The capability of the diamidophosphite to act as Rh-ligand was investigated in the formation of ionic as well as covalent Rh-complexes. The stereodinamic properties of these complexes were studied by VT-NMR spectroscopy.File in questo prodotto:
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