Interaction of common imines with WCl6 in organic solvents revealed very unusual features in the context of imine chemistry. Ph2=NH was converted in one pot into the 2-aza-allenium species [Ph2C=N=CPh2]+ via N2 release, with [Ph2C=NH2]+being a co-product. PhCH=NtBu underwent C-H bond activation resulting in the formation of [CN] containing derivatives, together with [PhCH=NHtBu]+
One pot conversion of benzophenone imine into the relevant 2-aza-allenium
Funaioli, Tiziana;Marchetti, Fabio
;Pampaloni, Guido;
2017-01-01
Abstract
Interaction of common imines with WCl6 in organic solvents revealed very unusual features in the context of imine chemistry. Ph2=NH was converted in one pot into the 2-aza-allenium species [Ph2C=N=CPh2]+ via N2 release, with [Ph2C=NH2]+being a co-product. PhCH=NtBu underwent C-H bond activation resulting in the formation of [CN] containing derivatives, together with [PhCH=NHtBu]+File in questo prodotto:
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126 - Chem Comm 2017 WCl6+imines.pdf
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