The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl6to react with N-(2,6-diisopropylphenyl) α-diimines, in CH2Cl2at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C-N coupling.
Allowing the direct interaction of: N -aryl α-diimines with a high valent metal chloride: One-pot WCl6-promoted formation of quinoxalinium salts
Bartalucci, Niccolò;Funaioli, Tiziana;Marchetti, Fabio
;Pampaloni, Guido;
2017-01-01
Abstract
The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl6to react with N-(2,6-diisopropylphenyl) α-diimines, in CH2Cl2at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C-N coupling.File in questo prodotto:
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