The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl6to react with N-(2,6-diisopropylphenyl) α-diimines, in CH2Cl2at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C-N coupling.

Allowing the direct interaction of: N -aryl α-diimines with a high valent metal chloride: One-pot WCl6-promoted formation of quinoxalinium salts

Bartalucci, Niccolò;Funaioli, Tiziana;Marchetti, Fabio
;
Pampaloni, Guido;
2017

Abstract

The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl6to react with N-(2,6-diisopropylphenyl) α-diimines, in CH2Cl2at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C-N coupling.
Bartalucci, Niccolò; Bortoluzzi, Marco; Funaioli, Tiziana; Marchetti, Fabio; Pampaloni, Guido; Zacchini, Stefano
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11568/877621
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