Two new triazole-pyridine-bistetrazolate ligands were synthesized via a versatile procedure that allows for further derivatization; their corresponding homoleptic tris-ligand nona-coordinated lanthanide complexes are highly luminescent in the solid state and in a PVA polymeric matrix with measured values for the luminescence quantum yield of 70(7) and 98(9)% for EuIIIand TbIII, respectively. © 2014 The Royal Society of Chemistry.
An efficient triazole-pyridine-bistetrazolate platform for highly luminescent lanthanide complexes
Pietro, S. DiPrimo
;
2014-01-01
Abstract
Two new triazole-pyridine-bistetrazolate ligands were synthesized via a versatile procedure that allows for further derivatization; their corresponding homoleptic tris-ligand nona-coordinated lanthanide complexes are highly luminescent in the solid state and in a PVA polymeric matrix with measured values for the luminescence quantum yield of 70(7) and 98(9)% for EuIIIand TbIII, respectively. © 2014 The Royal Society of Chemistry.File in questo prodotto:
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