Design of a pH-responsive conductive nanocomposite based on MWCNTs stabilized in water by amphiphilic block copolymers

Homogeneouswater dispersions ofmulti-walled carbon nanotubes (MWCNTs)were prepared by ultrasonication in the presence of an amphiphilic polystyrene-block-poly(acrylic acid) (PS-b-PAA) copolymer. The ability of PS-b-PAA to disperse and stabilizeMWCTNs was investigated by UV-vis, SEM and zeta potential. The results show that the addition of a styrene block to PAA enhances the dispersion efficiency of the graphitic filler compared to pure PAA, possibly due to the nanotube affinity with the polystyrene moiety. Notably, the dispersions show an evident pH-responsive behavior, being MWCNTs reaggregation promoted in basic environment. It isworth noting that the responsive character is maintained in solid composites obtained by drop casting, thus indicating potential applications in sensing.