Since safety hazards can occur during the life of a Li-ion battery, understanding its behavior under abusive conditions is important for the development of a safe cell. In this work, overcharge tests on commercial Li-polymer cells were conducted in a climatic chamber, resulting in gas evolution. A comprehensive post-mortem analysis of the abused cells was carried out: the exhaust gases were identified by gas phase chromatography coupled with a thermal conductivity detector (micro-GC/TCD), then flammable and toxic species were detected; the cathode and anode materials were analysed using scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS), while the electrolyte composition was studied by Fourier-transform infrared spectroscopy (FT-IR). Interestingly, the ambient temperature seemed to affect the degradation of the cell materials and hence the composition of the evolved gas.

Experimental analysis of overcharged Li-polymer batteries

Serena Ciorba
Primo
;
Mirko Marracci
Secondo
;
Claudia Antonetti;Gianluca Caposciutti;Bernardo Tellini;Anna Maria Raspolli Galletti
Ultimo
2020-01-01

Abstract

Since safety hazards can occur during the life of a Li-ion battery, understanding its behavior under abusive conditions is important for the development of a safe cell. In this work, overcharge tests on commercial Li-polymer cells were conducted in a climatic chamber, resulting in gas evolution. A comprehensive post-mortem analysis of the abused cells was carried out: the exhaust gases were identified by gas phase chromatography coupled with a thermal conductivity detector (micro-GC/TCD), then flammable and toxic species were detected; the cathode and anode materials were analysed using scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS), while the electrolyte composition was studied by Fourier-transform infrared spectroscopy (FT-IR). Interestingly, the ambient temperature seemed to affect the degradation of the cell materials and hence the composition of the evolved gas.
2020
Ciorba, Serena; Marracci, Mirko; Antonetti, Claudia; Martinelli, Marco; Caposciutti, Gianluca; Tellini, Bernardo; RASPOLLI GALLETTI, ANNA MARIA...espandi
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/1057023
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