Relaxation times tau(T,v) for different temperatures, T, and specific volumes, v, collapse to a master curve vs Tu(gamma), with gamma a material constant. The isochoric fragility, m(V), is also a material constant, inversely correlated with gamma. From these experimental facts, we obtain a three-parameter function that accurately fits tau(T,v) data for several glass-formers over the supercooled regime, without any divergence of tau below T(g). Although the values of the three parameters depend on the material, only gamma significantly varies; thus, by normalizing material-specific quantities related to gamma, a universal power law for the dynamics is obtained.

What can we learn by squeezing a liquid?

CAPACCIOLI, SIMONE;
2006-01-01

Abstract

Relaxation times tau(T,v) for different temperatures, T, and specific volumes, v, collapse to a master curve vs Tu(gamma), with gamma a material constant. The isochoric fragility, m(V), is also a material constant, inversely correlated with gamma. From these experimental facts, we obtain a three-parameter function that accurately fits tau(T,v) data for several glass-formers over the supercooled regime, without any divergence of tau below T(g). Although the values of the three parameters depend on the material, only gamma significantly varies; thus, by normalizing material-specific quantities related to gamma, a universal power law for the dynamics is obtained.
2006
Casalini, R.; Capaccioli, Simone; Roland, C. M.
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What can we learn by squeezing a liquid?

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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11568/106893
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