Relaxation times tau(T,v) for different temperatures, T, and specific volumes, v, collapse to a master curve vs Tu(gamma), with gamma a material constant. The isochoric fragility, m(V), is also a material constant, inversely correlated with gamma. From these experimental facts, we obtain a three-parameter function that accurately fits tau(T,v) data for several glass-formers over the supercooled regime, without any divergence of tau below T(g). Although the values of the three parameters depend on the material, only gamma significantly varies; thus, by normalizing material-specific quantities related to gamma, a universal power law for the dynamics is obtained.
What can we learn by squeezing a liquid?
CAPACCIOLI, SIMONE;
2006-01-01
Abstract
Relaxation times tau(T,v) for different temperatures, T, and specific volumes, v, collapse to a master curve vs Tu(gamma), with gamma a material constant. The isochoric fragility, m(V), is also a material constant, inversely correlated with gamma. From these experimental facts, we obtain a three-parameter function that accurately fits tau(T,v) data for several glass-formers over the supercooled regime, without any divergence of tau below T(g). Although the values of the three parameters depend on the material, only gamma significantly varies; thus, by normalizing material-specific quantities related to gamma, a universal power law for the dynamics is obtained.File | Dimensione | Formato | |
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What can we learn by squeezing a liquid?
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