The neutral cobalt(I) complex Co(py)2(η-BPh4) (py = pyridine) was obtained on removal of py and thf (thf = tetrahydrofuran) from [Co(py)3(thf)3][BPh4]2 and its crystal structure has been determined; in py as solvent, the former is converted into the ionic [Co(py)6][BPh4], which reduces CO 2 to CO and water to dihydrogen.
|Autori:||FACHINETTI G; FUNAIOLI T; ZANAZZI PF|
|Titolo:||Tetraphenylborate Anion Oxidation by Acidic Co2+ Cations: Synthesis and Properties of Pyridine-Cobalt(I) Compexes|
|Anno del prodotto:||1988|
|Digital Object Identifier (DOI):||10.1039/c39880001100|
|Appare nelle tipologie:||1.1 Articolo in rivista|