The neutral cobalt(I) complex Co(py)2(η-BPh4) (py = pyridine) was obtained on removal of py and thf (thf = tetrahydrofuran) from [Co(py)3(thf)3][BPh4]2 and its crystal structure has been determined; in py as solvent, the former is converted into the ionic [Co(py)6][BPh4], which reduces CO 2 to CO and water to dihydrogen.
Tetraphenylborate Anion Oxidation by Acidic Co2+ Cations: Synthesis and Properties of Pyridine-Cobalt(I) Compexes
FACHINETTI, GIUSEPPE;FUNAIOLI, TIZIANA;
1988-01-01
Abstract
The neutral cobalt(I) complex Co(py)2(η-BPh4) (py = pyridine) was obtained on removal of py and thf (thf = tetrahydrofuran) from [Co(py)3(thf)3][BPh4]2 and its crystal structure has been determined; in py as solvent, the former is converted into the ionic [Co(py)6][BPh4], which reduces CO 2 to CO and water to dihydrogen.File in questo prodotto:
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