Glycerol is one of the glass-forming liquids selected by Robert H. Cole in 1950 to start his study of molecular dynamics by dielectric spectroscopy. Seventy-one years have gone by and remarkably no consensus has been reached on the nature and identity of the relaxation processes observed in the dielectric spectra. The macroscopic dielectric relaxation data allow different interpretations to yield contrasting results, and it is not possible to determine which one is most plausible. Coming to the rescue is the application of the nuclear ?? -resonance timeTDI data potentially can decide which interpretation of the dielectric spectra of glycerol is most plausible. The attempt was made by Saito et al., but there is a problem in their analysis of the dielectric data of glycerol and hence their conclusion is untenable. In this paper, we critically compare four major interpretations with the TDI data in an effort to identify the most plausible interpretation of the relaxation processes constituting the dielectric spectra of glycerol.
Arriving at the most plausible interpretation of the dielectric spectra of glycerol with help from quasielastic gamma-ray scattering time-domain interferometry
Capaccioli, S;
2022-01-01
Abstract
Glycerol is one of the glass-forming liquids selected by Robert H. Cole in 1950 to start his study of molecular dynamics by dielectric spectroscopy. Seventy-one years have gone by and remarkably no consensus has been reached on the nature and identity of the relaxation processes observed in the dielectric spectra. The macroscopic dielectric relaxation data allow different interpretations to yield contrasting results, and it is not possible to determine which one is most plausible. Coming to the rescue is the application of the nuclear ?? -resonance timeTDI data potentially can decide which interpretation of the dielectric spectra of glycerol is most plausible. The attempt was made by Saito et al., but there is a problem in their analysis of the dielectric data of glycerol and hence their conclusion is untenable. In this paper, we critically compare four major interpretations with the TDI data in an effort to identify the most plausible interpretation of the relaxation processes constituting the dielectric spectra of glycerol.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.