Relaxation in glass-forming substances is necessarily a many-body problem because of intermolecular interactions and constraints. Results from molecular dynamics simulations and experiments are used to reveal the critical elements and general effects originating from many-body relaxation, but not dealt with in conventional theories of the glass transition. Although many-body relaxation is still an unsolved problem in statistical mechanics, these critical elements and general effects will serve as guides to the construction of a satisfactory theory of the glass transition. This effort is aided by concepts drawn from the coupling model, whose predictions have been shown to be consistent with experimental facts.
Guides to solving the glass transition problem
CAPACCIOLI, SIMONE;
2008-01-01
Abstract
Relaxation in glass-forming substances is necessarily a many-body problem because of intermolecular interactions and constraints. Results from molecular dynamics simulations and experiments are used to reveal the critical elements and general effects originating from many-body relaxation, but not dealt with in conventional theories of the glass transition. Although many-body relaxation is still an unsolved problem in statistical mechanics, these critical elements and general effects will serve as guides to the construction of a satisfactory theory of the glass transition. This effort is aided by concepts drawn from the coupling model, whose predictions have been shown to be consistent with experimental facts.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
